Bazı 3-Alkil(Aril)-4-(3-asetoksibenzilidenamino)-4,5-dihidro-1H-1,2,4-triazol-5-on Bileşiklerinin Susuz Ortam Titrasyonları

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3-Phenyl-1H-1,2,4-triazol-5-amine–5-phenyl-1H-1,2,4-triazol-3-amine (1/1)

In the title compound, C(8)H(8)N(4)·C(8)H(8)N(4), two tautomers, viz. 3-phenyl-1,2,4-triazol-5-amine and 5-phenyl-1,2,4-triazol-3-amine, are crystallized together in equal amounts. The 3-phenyl-1,2,4-triazol-5-amine mol-ecule is essentially planar; the phenyl ring makes a dihedral angle of 2.3 (2)° with the mean plane of the 1,2,4-triazole ring. In the 5-phenyl-1,2,4-triazol-3-amine tautomer, t...

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5-Amino-1H-1,2,4-triazol-4-ium-3-carboxyl­ate hemihydrate

The asymmetric unit of the title compound, C(3)H(4)N(4)O(2)·0.5H(2)O, comprises two whole mol-ecules of 5-amino-1H-1,2,4-triazole-3-carb-oxy-lic acid in its zwitterionic form (proton transfer occurs from the carb-oxy-lic acid group to the N hetero-atom at position 1), plus one water mol-ecule of crystallization. The organic moieties are disposed into supra-molecular layers linked by N-H⋯O and N...

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3-Benzyl­sulfanyl-1H-1,2,4-triazol-5-amine

In the title mol-ecule, C(9)H(10)N(4)S, the dihedral angle between the benzene and triazole rings is 81.05 (5)°. In the crystal, N-H⋯N hydrogen bonds link the mol-ecules into infinite zigzag chains along [010].

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3-Benzyl­sulfanyl-5-(4-phenyl-1H-1,2,3-triazol-1-ylmeth­yl)-4H-1,2,4-triazol-4-amine

The mol-ecule of the title compound, C(18)H(17)N(7)S, is non-planar, with a dihedral angle of 71.4 (4)° between the two triazole rings, and an angle of 15.5 (3)° between the two phenyl rings. An intra-molecular N-H⋯S hydrogen bond forms a five-membered ring.

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4-(3-Methoxy­phen­yl)-3-[2-(4-methoxy­phen­yl)eth­yl]-1H-1,2,4-triazol-5(4H)-one

The asymmetric unit of the title compound, C(18)H(19)N(3)O(3), contains two crystallographically independent but similar mol-ecules. The triazole ring is oriented with respect to the benzene rings to form dihedral angles of 57.96 (6) and 7.01 (6)° in one mol-ecule, and 64.37 (5) and 10.73 (5)° in the other. The two independent mol-ecules are linked into a dimer by inter-molecular N-H⋯O hydrogen...

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ژورنال

عنوان ژورنال: SDÜ Fen Bilimleri Enstitüsü Dergisi

سال: 2016

ISSN: 1308-6529,1300-7688

DOI: 10.19113/sdufbed.31907